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Recently Asked General Chemistry Questions
Expert help when you need it- Q1:1 roac S Ily Neutral Solution pH of . It is said to be neutral. • This means that there are as many H* as OH. are neutral. and • Pure . is neither acidic or basic.See Answer
- Q2:Buffers Substances that change_____in pH. _____H+ when pH is to low (acidic). _______H+ when pH is to high (basic). See Answer
- Q3:Fill in the Blank: Element Indium In Y S Rubidium Rb Argon Yttrium Sulfur Symbol Protons 1+ Ar 37 Neutrons 50 22 Electrons Atomic Number 49 18 39 16 Atomic Mass 114 32 85See Answer
- Q4:1. The number of protons represents the a. atomic mass b. atomic number c. atomic weight d. atomic Isotope 2. The number of electrons in an element equals a. the number of neutrons b. the number of protons c. the number of protons + neutrons d. the number of protons-neutrons 3. An element has an atomic number of 25. That element is a. Na b. Sr c. Mn d. Cr 4. One proper way to indicate an isotope of Si with an atomic mass of 28 is a. 28-SI b. Si-28 C. 285 28 Si d. 5. How many neutrons are in the nucleus of Mo? a. 53 b. 42 c. 48 U.S4See Answer
- Q5: 3) Write the expression of base dissociation constant for the following reaction point out the conjugate acid: \mathrm{NH}_{3}(\mathrm{aq})+\mathrm{H}_{2} \mathrm{O}(\mathrm{l}) \rightleftharpoons \mathrm{NH}_{4}^{+}(\mathrm{aq})+\mathrm{OH}^{-}(\mathrm{aq})See Answer
- Q6: The reaction of cyclohexadiene with acrolein is shown below. Use Frontier Molecular Orbital Theory (showing relevant orbital interactions) to explain why this reaction favours the endo product 18. Explain, using energy levels, why the reaction of cyclohexadiene proceedsrapidly with acrolein than with ethene.more Explain, using energy levels, why the reaction below, between an electron-deficient diene and an electron-rich alkene, occurs readily. Draw the structure, including stereochemistry, of the product 19 of the reaction below. Draw a 'curly' arrow mechanism and draw the transition state leading to See Answer
- Q7: The industrial production of sulfuric acid involves several steps. One of these steps is the reaction of sulfur dioxide, SO2, with oxygen to form sulfur trioxide, SO3. 250,(g) + O:(g) = 250,(g) he reaction to produce sulfur trioxide reaches an equilibrium. 250,(g) + 0,(g)- 250,(g) The forward reaction is exothermic. The rate of attainment of equilibrium and the equilibrium yield of sulfur trioxide are affected by pressure and temperature. A manufacturer considered two sets of conditions, A and B, for this reaction.In each case sulfur dioxide is mixed with excess oxygen.The manufacturer changed the temperature and the pressure and only used a catalyst in B.The sets of conditions A and B are shown in Figure 7. The manufacturer chooses set of conditions B rather than set of conditions A. Explain, by considering the effect of changing the conditions on the rate of attainment of equilibrium andon the equilibrium yield of sulfur trioxide, why the manufacturer chooses the set of conditions B ratherthan the set of conditions A.See Answer
- Q8: 2 Sodium hydride, NaH, can be used to generate hydrogen for fuel cells. (a) In order to calculate the first electron affinity of hydrogen, a student was asked to draw a Born-Haber cycle for sodium hydride. The cycle had two errors but the numerical data were correct. (i) Identify and correct the two errors in this Born-Haber cycle. (ii) Calculate the first electron affinity, in kJmol", of hydrogen, using the values given in the cycle. (b) The equation for the formation of sodium hydride is \mathrm{Na}(\mathrm{s})+1 / 2 \mathrm{H}_{2}(\mathrm{q}) \rightarrow \mathrm{NaH}(\mathrm{s}) \quad \Delta_{\mathrm{f}} H^{\theta}=-56 \mathrm{~kJ} \mathrm{~mol}^{-1} \text { The standard entropy change of the system, } \Delta S_{\text {system }}^{\ominus}, \text { for this reaction is } -76.5 \mathrm{JK}^{-1} \mathrm{~mol}^{-1} i) Deduce the feasibility of this reaction at 298 K by calculating the free energy change, AG.וא) \text { Calculate the temperature at which } \Delta G=0 (c) The sodium hydride is crushed in the presence of water to release the hydrogen gas for a fuel cell. The overall equation for the reaction occurring in the fuel cell is \mathrm{H}_{2}(\mathrm{~g})+1 / \mathrm{O}_{2}(\mathrm{~g}) \rightarrow \mathrm{H}_{2} \mathrm{O}(\mathrm{l}) In an alkaline fuel cell the oxidation half-equation is \mathrm{H}_{2}(\mathrm{~g})+2 \mathrm{OH}^{-}(\mathrm{aq}) \rightarrow 2 \mathrm{H}_{2} \mathrm{O}(\mathrm{l})+2 \mathrm{e}^{-} Deduce the reduction half-equation for the alkaline fuel cell.See Answer
- Q9: Many metals corrode. An experiment is carried out to see if magnesium ribbon wrapped around a piece of iron rod has an effect on the rate at which the iron rod rusts. The apparatus is shown in Figure 4. The method used is an iron rod, with magnesium ribbon wrapped around it, is placed in a boiling tube labelled A 10 cm3 water from a measuring cylinder is poured into this boiling tube an identical rod but with no magnesium ribbon wrapped around it is placed in a second boiling tube labelled B Both boiling tubes are left for a few days. (i) Explain why iron rod rather than stainless steel rod is used in this experiment. (iii) After a few days the two boiling tubes were examined. (ii) State why it is not necessary to use a pipette to measure out 10 cm3 water in this experiment.See Answer
- Q10: Q4) Consider the following pH curve: a) Explain if the analyte used to obtain the following pH curve was strong or weak, an acid or a base, monoprotic or polyprotic and HOW YOU KNOW (i.e.what were the give away clues.) b) What would be an appropriate indicator for this reaction? Explain why.See Answer
- Q11: Into a beaker of ultrapure water, 20 mL of hexane is added. A high-speed stirrer thencauses the hexane to be distributed into a dispersion of droplets, each of radius 1 um.If the water/hexane interfacial tension is 50.2 mN m-', how much work is done indispersing the oil? What is the pressure difference between the inside and outside of each droplet?See Answer
- Q12: Arrange the boiling points of the aqueous solutions, relative to pure water. Assume complete dissociation for the ionic compounds. See Answer
- Q13: Which drawing(s) represents a face-centered cubic unit cell? See Answer
- Q14: 14. The following table gives experimental boiling points for a series of compounds containing group 16 elements bonded to hydrogen atoms. a) (2 marks) Briefly explain the main reason why boiling point decreases from H2Te to H2Se to H2S. b) (1 mark) Briefly explain why H2O seemingly breaks this trend with a higher boiling point compared to most of the others. See Answer
- Q15: In which reaction is nitrogen reduced? \mathrm{Cu}^{2+}+2 \mathrm{NO}_{2}+2 \mathrm{H}_{2} \mathrm{O} \rightarrow \mathrm{Cu}+4 \mathrm{H}^{+}+2 \mathrm{NO}_{3}^{-} \mathrm{Q} 4 \mathrm{Zn}+10 \mathrm{H}^{+}+\mathrm{NO}_{3}^{-} \rightarrow 4 \mathrm{Zn}^{2+}+\mathrm{NH}_{4}{ }^{+}+3 \mathrm{H}_{2} \mathrm{O} 2 \mathrm{NO}+\mathrm{O}_{2} \rightarrow 2 \mathrm{NO}_{2} 4 \mathrm{NH}_{3}+5 \mathrm{O}_{2} \rightarrow 4 \mathrm{NO}+6 \mathrm{H}_{2} \mathrm{O}See Answer
- Q16: Methylamine ,CH3NH2, is a weak base with a K, value of 4. 37 × 10¬4 .Find the pH of a 3.75 mol/L solution. [8 marks T]See Answer
- Q17: Covalent substances can be simple molecular covalent or giant covalent. Oxygen, O2, is also a simple molecular, covalent substance. Draw a dot and cross diagram for the molecule of oxygen.See Answer
- Q18: Which of the following substances will be a solid at 20 °C and will melt when placed in a beaker of hot water at 80 °C? See Answer
- Q19: The concentration of dilute sulfuric acid can be determined by titration with sodium hydroxide solution of known concentration. 25.00 cm of dilute sulfuric acid was measured out using a pipette and transferred to a conical flask. A few drops of methyl orange indicator were added to the acid in the conical flask. Sodium hydroxidesolution was added to the acid from a burette until the indicator changed colour. The titration was repeated until two concordant results were obtained. The accurate result was the average of the two concordant results. A brief report of the practical method has been given above. Further detail can be added to this method to ensure that anyone following the method will obtain anaccurate result. Explain two details that could be added to this practical method to ensure an accurate result is obtained.See Answer
- Q20: Consider the following: NO2 → N2O3 The nitrogen atom in each NO2 O loses 1 electron loses 2 electrons gains 2 electrons gains 1 electronSee Answer
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